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脉冲电晕等离子体烟气脱硫工业试验研究

赵君科,王保健,任先文,朱祖良

《中国工程科学》 2002年第4卷第2期页码 74-78

摘要：

利用建造在四川绵阳科学城热电厂的最大烟气处理量为20000 m³/h的脉冲电晕等离子体烟气脱硫工业中试装置，研究了影响脱硫效率的因素，获得了最佳工艺参数。究结果表明，当烟气温度在65～70℃，烟气水分含量约10％，氨硫化学剂量比为1∶1，烟停留时间大于6 s、能耗低于5 Wh/Nm³等条件下，脱硫率达85％以上。

关键词：脉冲电晕放电脱硫工业中试

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Industrial-scale investigations on effects of tertiary-air declination angle on combustion and steam

Xiaoguang LI, Lingyan ZENG, Hongye LIU, Yao LI, Yifu LI, Yunlong ZHAO, Bo JIAO, Minhang SONG, Shaofeng ZHANG, Zhichao CHEN, Zhengqi LI

《能源前沿（英文）》 2021年第15卷第1期页码 132-142 doi: 10.1007/s11708-020-0803-z

摘要： Industrial-scale experiments were conducted to study the effects of tertiary air declination angle (TDA) on the coal combustion and steam temperature characteristics in the first 350-MW supercritical down-fired boiler in China with the multiple-injection and multiple-staging combustion (MIMSC) technology at medium and high loads. The experimental results indicated that as the TDA increased from 0° to 15°, the overall gas temperature in the lower furnace rose and the symmetry of temperature field was enhanced. The ignition distance of the fuel-rich coal/air flow decreased. In near-burner region, the concentration of O decreased while the concentrations of CO and NO increased. The concentration of NO decreased in near-tertiary-air region. The carbon in fly ash decreased significantly from 8.40% to 6.45% at a load of 260 MW. At a TDA of 15°, the ignition distances were the shortest (2.07 m and 1.73 m) at a load of 210 MW and 260 MW, respectively. The main and reheat steam temperatures were the highest (557.2°C and 559.4°C at a load of 210 MW, 558.4°C and 560.3°C at a load of 260 MW). The carbon in fly ash was the lowest (4.83%) at a load of 210 MW. On changing the TDA from 15° to 25°, the flame kernel was found to move downward and the main and reheat steam temperatures dropped obviously. The change of TDA has little effect on NO emissions(660–681 mg/m at 6% O ). In comprehensive consideration of the pulverized coal combustion characteristics and the unit economic performance, an optimal TDA of 15° is recommended.

关键词： supercritical down-fired boiler industrial-scale experiment tertiary air declination angle coal combustion steam temperature

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面向塑料回收的工业级PP/PE物理合金化技术 Article

瞿金平, 黄照夏, 杨智韬, 张桂珍, 殷小春, 冯彦洪, 何和智, 晋刚, 吴婷, 何光建, 曹贤武

《工程（英文）》 2022年第9卷第2期页码 95-100 doi: 10.1016/j.eng.2021.02.021

摘要：

聚丙烯（PP）和聚乙烯（PE）在日常生活中无处不在。但PP和PE的相容性较差，通过简单熔融共混难以制备具有良好力学性能的合金，为废弃PP、PE的回收再利用带来难题。此外，由于可能存在的环境污染问题，传统的添加相容剂诱导增容的方法也难以得到广泛应用。在本文中，受到中国传统榨油方法的启发，我们报道了一种简单的、可工业化的无添加制备高度取向蜂窝结构PP/PE 二元共混物的新技术。由于独特的蜂窝结构，共混物的力学性能高于其亲系材料，也高于采用传统密炼机制备的样品。因此，本文报道的方法不仅可以应用于不相容聚合物体系的物理增容，也可以为无添加、免分拣的废旧塑料回收提供一种新路径。我们期待通过该技术可以实现废弃塑料环境友好且可持续的循环高值利用。

关键词：聚丙烯聚乙烯物理合金化蜂窝结构

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Simulation and experimental improvement on a small-scale Stirling thermo-acoustic engine

Mao CHEN,Yonglin JU

《能源前沿（英文）》 2016年第10卷第1期页码 37-45 doi: 10.1007/s11708-015-0390-6

摘要： Compared with the traditional engines, the thermo-acoustic engines are relatively new and can act as the linear compressors for refrigerators. Many institutes have shown great interest in this kind of machine for its absence of moving mechanical part. In this paper, the influence of the dimensions of the main parts of the small-scale Stirling thermo-acoustic engine was numerically simulated using a computer code called DeltaEC. The resonator and the resonator cavity were found to be the most convenient and effective in improving the performance of the engine. Based on the numerical simulation, a small-scale Stirling thermo-acoustic engine were constructed and experimentally investigated. Currently, with a resonator length of only 1 m, the working frequency of the engine was decreased to 90 Hz and the onset temperature difference was decreased to 198.2 K.

关键词： thermo-acoustic Stirling engine small-scale simulation experiment

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Design and analysis of millimeters-scale omnidirectional mobile microrobot for microfactories

LI Jianghao, LI Zhenbo, CHEN Jiapin, LI Jianghao

《机械工程前沿（英文）》 2008年第3卷第2期页码 170-174 doi: 10.1007/s11465-008-0030-5

摘要： An omnidirectional mobile microrobot with a 9 mm × 8 mm × 8 mm size is introduced. The microrobot is driven by three electromagnetic micromotors with 2 mm diameter, two of which are for linear movement and the third one for steering. Dynamics is analyzed to present the relationship between the micromotor torque and the dual-wheel structure size as well as the frictions. Experiment results show that the microrobot payload ability can satisfy the requirements of conveying tasks in microfactories.

关键词： dual-wheel structure microrobot relationship electromagnetic Experiment

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Combined Fenton process and sulfide precipitation for removal of heavy metals from industrial wastewater: Bench and pilot scale studies focusing on in-depth thallium removal

Huosheng Li, Hongguo Zhang, Jianyou Long, Ping Zhang, Yongheng Chen

《环境科学与工程前沿（英文）》 2019年第13卷第4期 doi: 10.1007/s11783-019-1130-7

摘要：

Addition of alkali to pH 10 is effective for precipitation of precipitable metals.

Fenton treatment is effective for substantial removal of Tl, Cd, Cu, Pb, and Zn.

Sulfide precipitation is a final step for removal of trace Tl, Cd, Cu, Pb, and Zn.

Bench and pilot studies demonstrated the effectiveness of this combined technique.

关键词： Thallium Pilot Fenton Sulfide precipitation Heavy metal Industrial wastewater

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Full scale amendment of a contaminated wood impregnation site with iron water treatment residues

Sanne Skov NIELSEN, Peter KJELDSEN, Rasmus JAKOBSEN

《环境科学与工程前沿（英文）》 2016年第10卷第4期 doi: 10.1007/s11783-016-0842-1

摘要： Iron water treatment residues are a free by-product with high concentration of iron oxides Iron water treatment residues has a large potential for arsenic sorption Soils are highly contaminated by arsenic at wood preservation sites Iron water treatment residues were added to hot spots contaminated with arsenic The addition led to significant decrease in leaching of arsenic from the contaminated soil Iron water treatment residues (Fe-WTR) are a free by-product of the treatment of drinking water with high concentration of iron oxides and potential for arsenic sorption. This paper aims at applying Fe-WTR to a contaminated site, measuring the reduction in contaminant leaching, and discussing the design of delivery and mixing strategy for soil stabilization at field scale and present a cost-effective method of soil mixing by common contractor machinery. Soil contaminated by As, Cr, and Cu at an abandoned wood impregnation site was amended with 0.22% (dw) Fe-WTR. To evaluate the full scale amendment a 100 m test site and a control site (without amendment) were monitored for 14 months. Also soil analysis of Fe to evaluate the degree of soil and Fe-WTR mixing was done. Stabilization with Fe-WTR had a significant effect on leachable contaminants, reducing pore water As by 93%, Cu by 91% and Cr by 95% in the upper samplers. Dosage and mixing of Fe-WTR in the soil proved to be difficult in the deeper part of the field, and pore water concentrations of arsenic was generally higher. Despite water logged conditions no increase in dissolved iron or arsenic was observed in the amended soil. Our field scale amendment of contaminated soil was overall successful in decreasing leaching of As, Cr and Cu. With minor improvements in the mixing and delivery strategy, this stabilization method is suggested for use in cases, where leaching of Cu, Cr and As constitutes a risk for groundwater and freshwater.

关键词： Field experiment Iron oxide Arsenic Stabilization Wood preservation sites

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A pilot scale test of ozonization treatment of ethene wastewater for reuse

ZHONG Li, REN Wei, GUO Wenjing

《化学科学与工程前沿（英文）》 2008年第2卷第2期页码 191-195 doi: 10.1007/s11705-008-0028-x

摘要： A pilot scale test of advanced treatment of ethene wastewater by ozonization was carried out for industrial water reuse. Effects of different operating conditions on COD degradation, such as wastewater flow rate, ozonized gas flow rate, operating voltage of ozonizer and two ozone generation means, using pure oxygen or air, was investigated. The results show that the increase of ozonizer operating voltage, the decrease of wastewater flow rate and the suitable ozonized gas flow rate improve the removal of COD in wastewater and that ozone generated respectively from air and pure oxygen can effectively remove COD of ethene wastewater to meet the industrial water reuse criterion.

关键词： different industrial oxygen generation criterion

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Large-scale industrial manufacturing of carbon nanotubes in a continuous inclined mobile-bed rotating

Sophie L. Pirard, Sigrid Douven, Jean-Paul Pirard

《化学科学与工程前沿（英文）》 2017年第11卷第2期页码 280-289 doi: 10.1007/s11705-017-1635-1

摘要： This article reports the different steps of the design, development and validation of a process for continuous production of carbon nanotubes (CNTs) via catalytic chemical vapor deposition from the laboratory scale to the industrial production. This process is based on a continuous inclined mobile-bed rotating reactor and very active catalysts using methane or ethylene as carbon source. The importance of modeling taking into account the hydrodynamic, physicochemical and physical phenomena that occur during CNT production in the process analysis is emphasized. The impact of this invention on the environment and human health is taken into consideration too.

关键词： carbon nanotubes catalytic chemical vapor deposition inclined rotating reactor industrial process scaling-up

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Microalgal bioremediation of food-processing industrial wastewater under mixotrophic conditions: Kineticsand scale-up approach

Suvidha Gupta,R. A. Pandey,Sanjay B. Pawar

《化学科学与工程前沿（英文）》 2016年第10卷第4期页码 499-508 doi: 10.1007/s11705-016-1602-2

摘要： The microalgae were mixotrophically cultivated in an unsterilized and unfiltered raw food-processing industrial wastewater. Both inorganic carbon (CO -air) and organic carbon (wastewater) were provided simultaneously for microalgae growth. The aim of the study is to find out the utilization rates of total organic carbon (TOC) and chemical oxygen demand (COD) under mixotrophic conditions for a given waste water. About 90% reduction in TOC and COD were obtained for all dilutions of wastewater. Over 60% of nitrate and 40% of phosphate were consumed by microalgae from concentrated raw wastewater. This study shows that microalgae can use both organic and inorganic sources of carbon in more or less quantity under mixotrophic conditions. The growth of microalgae in food-processing industrial wastewater with all studied dilution factors, viz. zero (raw), 1.6 (dilution A), and 5 (dilution B) suggests that the freshwater requirement could be reduced substantially (20%–60%). The degradation kinetics also suggests that the microalgae cultivation on a high COD wastewater is feasible and scalable.

关键词： total organic carbon wastewater bioremediation kinetics mixotrophic cultivation

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Heat transfer in a large-scale circulating fluidized bed boiler

CHENG Leming, WANG Qinhui, SHI Zhenglun, LUO Zhongyang, NI Mingjiang, CEN Kefa

《能源前沿（英文）》 2007年第1卷第4期页码 477-482 doi: 10.1007/s11708-007-0071-5

摘要： Heat transfer of a furnace in a large-scale circulating fluidized bed (CFB) boiler was studied based on the analysis of available heat transfer coefficient data from typical industrial CFB boilers and measured data from a 12 MW

关键词： available coefficient industrial large-scale circulating analysis

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Experimental study on concrete box culverts in trenches

Baoguo CHEN, Junjie ZHENG, Jie HAN

《结构与土木工程前沿（英文）》 2009年第3卷第1期页码 73-80 doi: 10.1007/s11709-009-0008-3

摘要： Concrete box culverts are widely used in expressways in mountain areas. Many problems frequently take place due to improperly estimated vertical earth pressures on culverts. The prevailing Chinese General Code for Design of Highway Bridges and Culverts (CGCDHBC) stipulates the computation of the design load on culverts primarily based on the linear earth pressure theory, which cannot accurately describe the variation of the vertical load on culverts in trenches. In this paper, a full-scale experiment and numerical simulation were conducted to evaluate the variation of vertical earth pressures on culvert and soil arching in backfill. The variations of foundation pressure and settlement were also analyzed. The result revealed that the soil arch forms when the backfill on the culvert reaches a certain height. The soil arching effect reduces the stress concentration on the crown of the culvert but it is unstable. The vertical earth pressure on top of the culvert is significantly different from that recommended by the CGCDHBC

关键词： culvert vertical earth pressure soil arch full-scale experiment numerical simulation

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Carbonation of calcium-containing mineral and industrial by-products

Ron ZEVENHOVEN, Anders WIKLUND, Johan FAGERLUND, Sanni ELONEVA, Ben IN’T VEEN, Gert VAN MOSSEL, Harold BOERRIGTER, Hans GEERLINGS

《化学科学与工程前沿（英文）》 2010年第4卷第2期页码 110-119 doi: 10.1007/s11705-009-0238-x

摘要： The use of carbon dioxide (CO) and calcium-containing by-products from industrial activities is receiving increasing interest as a route to valuable carbonate materials while reducing CO emissions and saving natural resources. In this work, wet-chemical experimental data was assessed, which involved the carbonation of three types of materials in aqueous solutions, namely, 1) wollastonite, a calcium silicate mineral, 2) steelmaking slag, a by-product of steel production, and 3) paper bottom ash (PBA) from waste paper incineration. Aims were to achieve either a high carbonation degree and/or a pure carbonate product with potential commercial value. Producing a pure precipitated calcium carbonate (PCC) material that may find use in paper industry products puts strong requirements on purity and brightness. The parameters investigated were particle size, CO pressure, temperature, solid/liquid ratio, and the use of additives that affect the solubilities of CO and/or calcium carbonate. Temperatures and pressures were varied up to 180°C and 4 Mpa. Data obtained with the wollastinite mineral allowed for a comparison between natural resources and the industrial by-product materials, the latter typically being more reactive. With respect to temperature and pressure trends reported by others were largely confirmed, with temperatures above 150°C introducing thermodynamic limitations depending on CO pressure. The influence of additives showed some promise, although costs may make recycling and reuse of additives a necessity for a large-scale process. When using steelmaking slag, magnetic separation may remove some iron-containing material from the process (although this is far from perfect), while the addition of bicarbonate supported the removal of phosphorous, aside from improving calcium extraction. The experiments with paper bottom ash (PBA) gave new data, showing that its reactivity resembles that of steelmaking slag, while its composition results in relatively pure carbonate product. Also, with PBA no additives were needed to achieve this.

关键词： industrial separation large-scale steelmaking recycling

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Preparation and application of a phosphorous free and non-nitrogen scale inhibitor in industrial cooling

Guangqing LIU,Mengwei XUE,Jingyi HUANG,Huchuan WANG,Yuming ZHOU,Qingzhao YAO,Lei LING,Ke CAO,Yahui LIU,Yunyun BU,Yiyi CHEN,Wendao WU,Wei SUN

《环境科学与工程前沿（英文）》 2015年第9卷第3期页码 545-553 doi: 10.1007/s11783-014-0657-x

摘要： A novel environmentally friendly type of calcium carbonate, zinc (II) and iron (III) scale inhibitor Acrylic acid- allylpolyethoxy carboxylate copolymer (AA-APEL) was synthesized. The anti-scale property of the AA-APEL toward CaCO , zinc (II) and iron (III) in the artificial cooling water was studied through static scale inhibition tests. The observation shows that both calcium carbonate, zinc (II) and iron (III) inhibition increase with increasing the dosage of AA-APEL. The effect on formation of CaCO was investigated with combination of scanning electronic microscopy (SEM), transmission electron microscopy (TEM), X-ray powder diffraction (XRD) analysis and fourier transform infrared spectrometer, respectively. The results showed that the AA-APEL copolymer not only influenced calcium carbonate crystal morphology and crystal size but also the crystallinity. The crystallization of CaCO in the absence of inhibitor was rhombohedral calcite crystal, whereas a mixture of calcite with vaterite crystals was found in the presence of the AA-APEL copolymer. Inhibition mechanism is proposed that the interactions between calcium or iron ions and polyethylene glycol (PEG) are the fundamental impetus to restrain the formation of the scale in cooling water systems.

关键词： phosphorous free calcium carbonate stabilize zinc (II) disperse iron (III) cooling water

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CO气相偶联制草酸模拟放大研究

王保伟,马新宾,李振花,许根慧

《中国工程科学》 2001年第3卷第2期页码 79-85

摘要：

CO气相偶联制草酸为多步反应循环系统。在评选出最佳催化剂及理论研究的基础上，利用模拟计算、催化剂工程研究和模试运转对CO气相偶联合成草酸二乙酯的工程问题进行了研究，解决了偶联反应和再生反应速率匹配的关键技术。在反应动力学和反应参数敏感性分析的基础上，经模试1000小时连续运转，解决了复杂反应的非线性多步循环的速率匹配，并建立了零排放洁净工艺过程；研制的催化剂适用于CO偶联反应工业放大工程，为工业生产提供了一条绿色化学工艺路线。

关键词： CO 偶联草酸模试放大催化剂工程

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标题作者时间类型操作

脉冲电晕等离子体烟气脱硫工业试验研究

赵君科,王保健,任先文,朱祖良

期刊论文

Industrial-scale investigations on effects of tertiary-air declination angle on combustion and steam

Xiaoguang LI, Lingyan ZENG, Hongye LIU, Yao LI, Yifu LI, Yunlong ZHAO, Bo JIAO, Minhang SONG, Shaofeng ZHANG, Zhichao CHEN, Zhengqi LI

期刊论文

面向塑料回收的工业级PP/PE物理合金化技术

瞿金平, 黄照夏, 杨智韬, 张桂珍, 殷小春, 冯彦洪, 何和智, 晋刚, 吴婷, 何光建, 曹贤武

期刊论文

Simulation and experimental improvement on a small-scale Stirling thermo-acoustic engine

Mao CHEN,Yonglin JU

期刊论文

Design and analysis of millimeters-scale omnidirectional mobile microrobot for microfactories

LI Jianghao, LI Zhenbo, CHEN Jiapin, LI Jianghao

期刊论文

Combined Fenton process and sulfide precipitation for removal of heavy metals from industrial wastewater: Bench and pilot scale studies focusing on in-depth thallium removal

Huosheng Li, Hongguo Zhang, Jianyou Long, Ping Zhang, Yongheng Chen

期刊论文

Full scale amendment of a contaminated wood impregnation site with iron water treatment residues

Sanne Skov NIELSEN, Peter KJELDSEN, Rasmus JAKOBSEN

期刊论文

A pilot scale test of ozonization treatment of ethene wastewater for reuse

ZHONG Li, REN Wei, GUO Wenjing

期刊论文

Large-scale industrial manufacturing of carbon nanotubes in a continuous inclined mobile-bed rotating

Sophie L. Pirard, Sigrid Douven, Jean-Paul Pirard

期刊论文

Microalgal bioremediation of food-processing industrial wastewater under mixotrophic conditions: Kineticsand scale-up approach